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Q.1) What are the economics of galvanised reinforcement in concrete?

When frequent repair costs and consequences of corrosion damage to a reinforced concrete building are analyzed, the extra cost of galvanising is small. It can be regarded as an ‘insurance premium’, but a premium which is low and needs to be paid once only. Currently, the cost of galvanising of rebar is approximately Rs.8000 per tonne of steel, and this depends on the quantity to be galvanised, bar diameter etc.

While the cost of galvanising is an important factor, the cost of galvanised reinforcement as a percentage of total building cost is much lower than generally realized. It is as low as 0.5 – 1.0% in many cases. When related to total project costs, the added cost of galvanising becomes very small indeed. Such costs represent a very small proportion of the cost of repairs should unprotected reinforcement corrode. Frequently such repairs eliminate only the visible damage and cannot be relied upon as a long-term solution.

For most structures, even in the most aggressive environments, the use of galvanised reinforcement can be confined to the exposed surfaces and critical structural elements such as:

· Thin pre-cast cladding elements
· Facades of prestigious buildings
· Surface exposed beams and columns
· Windows and door surrounds
· Prefabricated units
· External facades of buildings near the sea coast
· Architectural features
Accordingly, whenever there is concern that premature corrosion of reinforcement might occur, reinforcement should be galvanised. The use of galvanising however should not be considered as an alternative to the provision of an adequate cover of dense, impermeable concrete.
Q.2)

What are the supply chain dynamics?

galvanising is done by galvanisers under the guidance of Indian Lead Zinc Development Association and Hindustan Zinc and after a comprehensive study of the facilities and quality of work done. All the work is done in adherence to standards prescribed by the BIS and ILZDA. The feedback received on basis of prior work carried out by the galvanizers is also considered while suggesting a galvanising facility for a project.

Currently the total capacities available for galvanised rebars are 75,000 to 80,000 tons per year, which is approximately 6,000-7,000 tons per month. With expansions taking place it is likely to touch 1, 00,000 tons per year.

The galvanising facilities are located across the country, which ensures that galvanised steel is available with minimum lead-time. This also ensures that the buyer incurs minimum transportation cost.

Q.3) What are the factors determining the durability of reinforcement?
Environment:

The external environment of the concrete provides the agents, which commonly cause corrosion in reinforcement: oxygen, water, carbon dioxide and chloride ions.

Marine structures and other structures close to coastal areas are particularly at risk from corrosion of reinforcement due to the ingress of chloride ions from sea spray and salt-laden air.

Away from the seacoast, corrosion of reinforcement in concrete is mostly due to the process of carbonation, which reduces the alkalinity of the surrounding concrete. This process can occur at any geographic location. The rate of carbonation is at a maximum when the relative humidity is about 50 per cent, and increases with increasing temperature. Recent surveys have shown that the corrosion problem in relatively new buildings is worst in coastal areas.

Carbonation resistance:

galvanised reinforcement is better able to resist the effects of carbonation because of the much wider range of pH (to about 8) over which the zinc coating remains passivated. Since black steel typically depassivates when the pH of concrete drops below about 11.5, it is apparent that as the carbonation ‘front’ moves past a galvanised rebar, little or no effect will occur until the concrete adjacent to the reinforcement is almost completely neutralized.

Chloride tolerance:

Though zinc can be depassivated and attacked in the presence of chloride ions, the tolerance of galvanised reinforcement to chloride depassivation is substantially higher than that of black steel. In a survey of a number of long-serving marine structures [Tonini, DE and Cook, AR ‘The performance of galvanised reinforcement in high chloride environments - field study reports.’ International Corrosion Forum, NACE, Houston], galvanised bars were shown to have been exposed to chloride contents as high as 2.2% (by approximately weight of cement) over periods of 10-20 years, with less than 10% loss of original coating thickness and no record of failure. This should be compared to chloride levels in the range of 0.2-0.3% by weight of cement leading to severe corrosion of black steel in similar circumstances.

Reaction between galvanised coatings and concrete:

During initial contact of galvanised reinforcement with wet concrete, the outer zinc layers of the galvanised coating react to form stable insoluble zinc salts (Fig-1). Attack ceases as the concrete hardens and the galvanised coating remains intact. This surface layer increases the bond strength of the rebar.
Corrosion rate of location and planned application life should be used to determine use of corrosion protection
The above study shows that the entire coastal belt of India (e.g. Mumbai, Chennai, Kolkatta, Gujarat, Goa, Kerala and other coastal regions) requires corrosion protection for the steel reinforcements as the rate of corrosion is quite high.

Bond strength of concrete to galvanised reinforcing bars:

The results of extensive programs of pull-out testing by a number of researchers reveal no significant difference in the bond strengths of black and galvanised steel deformed (i.e. ribbed) reinforcing bars in concrete.

Tests made by the Building Research Establishment in the UK show that, based on the work of five investigators, adhesion to concrete of plain reinforcing bars is on average:
 

  Hot dip galvanised steel

3.3 - 3.6 MPa
 
 

  Black steel

3 - 4.8 MPa

 
The large spread for black steel stems from different degrees of rust and different amounts of oxide scale on the steel surfaces.

In the case of deformed bar, the approximate stress at which 0.1 mm of slip occurs was found to be:
 

  Black steel

150 MPa
 
 

  Hot dip galvanised steel

160 MPa

 
 

  Hot dip galvanised steel (chromated)

190 MPa

 
The bond strength to concrete has also been studied in tests conducted by the University of California in accordance with American Concrete Institute (ACI) standard 208-58. Both corroded and uncorroded rebar were used. Tests were on concrete beams with plain or deformed bars cast inverted in the top of the beam. galvanised rebars show equal or better bond strength than ungalvanised rebars in all conditions in both plain and deformed types.

Passivation and additives:

The research into bond strengths also shows that the addition of chromates to the concrete mix in the ratio of 35-150 ppm by weight of cement increases the bond strength of galvanised plain bars significantly
 
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